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1.
Environ Sci Pollut Res Int ; 30(38): 89794-89804, 2023 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-37458887

RESUMO

This paper offers an experimental investigation of the effect of metal foam on the thermal and hydrodynamic performance of a parabolic trough collector (PTC). Metal foams play a crucial role in heat transfer improvement due to their high thermal conductivity. Three different arrangements of metal foams are applied inside the absorber tube of the PTC. The flow regime in the absorber tube is laminar at different Reynolds numbers of 422, 844, 1267, and 1689. Experimental tests are designed with Design-Expert software in which the response surface method is utilized. Experimental results revealed that maximum enhancement in thermal efficiency is related to the periodic array arrangement of the metal foam inside the tube. This arrangement leads to a 14% increase in thermal efficiency. However, in this arrangement, the friction factor increases considerably compared to a plain receiver tube.


Assuntos
Temperatura Alta , Hidrodinâmica , Metais , Condutividade Térmica
2.
Biosensors (Basel) ; 12(7)2022 Jun 28.
Artigo em Inglês | MEDLINE | ID: mdl-35884270

RESUMO

One of the most effective ways to detect and measure antibiotics is to detect their biomarkers. The best biomarker for the control and detection of oxytetracycline (OTC) is the OTC-specific aptamer. In this study, a novel, rapid, and label-free aptamer-based electrochemical biosensor (electrochemical aptasensor) was designed for OTC determination based on a newly synthesized nanocomposite including multi-walled carbon nanotubes (MWCNTs), gold nanoparticles (AuNPs), reduced graphene oxide (rGO), and chitosan (CS), as well as nanosheets to modify a glassy carbon electrode, which extremely enhanced electrical conductivity and increased the electrode surface to bind well with the amine-terminated OTC-specific aptamer through self-assembly. The (MWCNTs-AuNPs/CS-AuNPs/rGO-AuNPs) nanocomposite modified electrode was synthesized using a layer- by-layer modification method which had the highest efficiency for better aptamer stabilization. Differential pulse voltammetry (DPV), cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and scanning electron microscopy (SEM) techniques were used to investigate and evaluate the electrochemical properties and importance of the synthesized nanocomposite in different steps. The designed aptasensor was very sensitive for measuring the OTC content of milk samples, and the results were compared with those of our previously published paper. Based on the calibration curve, the detection limit was 30.0 pM, and the linear range was 1.00-540 nM for OTC. The repeatability and reproducibility of the aptasensor were obtained for 10.0 nM of OTC with a relative standard deviation (RSD%) of 2.39% and 4.01%, respectively, which were not affected by the coexistence of similar derivatives. The measurement in real samples with the recovery range of 93.5% to 98.76% shows that this aptasensor with a low detection limit and wide linear range can be a good tool for detecting OTC.


Assuntos
Aptâmeros de Nucleotídeos , Técnicas Biossensoriais , Grafite , Nanopartículas Metálicas , Nanotubos de Carbono , Oxitetraciclina , Aptâmeros de Nucleotídeos/química , Técnicas Biossensoriais/métodos , Técnicas Eletroquímicas/métodos , Eletrodos , Ouro/química , Grafite/química , Limite de Detecção , Nanopartículas Metálicas/química , Nanotubos de Carbono/química , Reprodutibilidade dos Testes
3.
Biosensors (Basel) ; 10(3)2020 Mar 11.
Artigo em Inglês | MEDLINE | ID: mdl-32168735

RESUMO

In this paper, an electrochemical technique is introduced for the determination of streptomycin (STR) in the presence of oxytetracycline (OTC) in milk samples. A novel bifunctional modified screen-printed electrode (SPE) modified with oracet blue, silver nanoparticles, and graphene oxide (OB/SNPs/GO/SPE) was fabricated. The modified electrode plays a catalyzer role for electrooxidation of STR at pH = 7.0 and reveals a facile a separation between the oxidation peaks of STR and OTC. Calculation of kinetic parameters such as the electron transfer coefficient α and the heterogeneous rate constant k´ of STR at the OB/SNPs/GO/SPE as 8.1 ± 0.07 cm s-1 and 0.32 have been obtained based on the theoretical model of Andrieux and Saveant. A differential pulse voltammetric measurement demonstrates two linear dynamic ranges, 0.4 to 240.0 nM and 240.0 to 720.0 nM and a detection limit of 0.17 nM for STR. The sensitivities of the OB/SNPs/GO/SPE towards the oxidation of STR in the absence and presence of OTC were 2.625 × 10-1 and 2.633 × 10-1 µA/µM, respectively.


Assuntos
Técnicas Eletroquímicas/métodos , Grafite/química , Nanopartículas Metálicas/química , Oxitetraciclina/uso terapêutico , Prata/química , Estreptomicina/uso terapêutico , Humanos , Oxitetraciclina/farmacologia , Estreptomicina/farmacologia
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